Numerical study of natural gas hydrate dissociation in a laboratory sandstone sample under a depression regime
https://doi.org/10.25587/SVFU.2023.59.65.006
Abstract
The present work covers mathematical modeling of the process of dissociation (decomposition) of natural gas hydrate of the Sredneviluysky gas condensate field in a laboratory sample of natural sandstone. Initially, the porous medium, filled with natural gas, water, and hydrate, is in thermobaric conditions meeting the stable state of the gas hydrate. Then, the pressure is released from one side of the cylindrical hydrate sample, which causes its decomposition. The mathematical model of the decomposition process takes into account the two-phase filtration of gas and water, the throttling effect, convective heat exchange, heat absorption during hydrate dissociation, and the kinetics of this process. The developed model and its implementation algorithm are tested against the results of a known experimental work. As a result of the computational experiment, distributions of gas pressure and temperature, hydrate and water saturation are obtained. Furthermore, the duration of the hydrate dissociation process is estimated with varying some initial parameters.
About the Authors
V. A. IvanovRussian Federation
Victor A. Ivanov
2 Petrovsky Street, 677980 Yakutsk
I. I. Rozhin
Russian Federation
Igor I. Rozhin
2 Petrovsky Street, 677980 Yakutsk
References
1. Tsypkin G. G., “Analytical solution of the nonlinear problem of gas hydrate dissociation in a formation,” Fluid Dyn., 42, No. 5, 798–806 (2007).
2. Vasil’ev V. I., Popov V. V., and Tsypkin G. G., “Numerical investigation of the decomposition of gas hydrates coexisting with gas in natural reservoirs ,” Fluid Dyn., 41, No. 4, 599–605 (2006).
3. Sun X., Nanchary N., and Mohanty K. K., “1-D modeling of hydrate depressurization in porous media,” Transp. Porous Media, 58, No. 3, 315–338 (2005).
4. Kim H. C., Bishnoi P. R., Heidemann R. A., and Rizvi S. S., “Kinetics of methane hydrate decomposition,” Chem. Eng. Sci., 42, No. 7, 1645–1653 (1987).
5. Sloan E. D., Clathrate Hydrates of Natural Gases, Marcel Dekker, New York (1998).
6. Brooks R. H. and Corey A. T., “Hydraulic properties of porous media,” Hydrology Papers, No. 3, Colorado State Univ., Fort Collins, CO (1964).
7. Masuda Y., “Modeling and experimental studies on dissociation of methane gas hydrates in Berea sandstone cores,” Proc. 3rd Int. Conf. Gas Hydrates, Salt Lake City, UT (1999).
8. Selim M. S. and Sloan E. D., “Heat and mass transfer during the dissociation of hydrates in porous media,” AIChE J., 35, No. 6, 1049–1052 (1989).
9. Sun X. and Mohanty K. K., “Kinetic simulation of methane hydrate formation and dissociation in porous media,” Chem. Eng. Sci., 61, No. 11, 3476–3495 (2006).
10. Ruan X., Song Y., Zhao J., Liang H., Yang M., and Li Y., “Numerical simulation of methane production from hydrates induced by different depressurizing approaches,” Energies, 5, No. 2, 438–458 (2012).
11. Musakaev N. G., Khasanov M. K., Borodin and S. L., “The mathematical model of the gas hydrate deposit development in permafrost,” Int. J. Heat Mass Transfer, 118, 455–461 (2018).
12. Musakaev N. G., Khasanov M. K., Borodin S. L., and Belskikh D. S., “Numerical investigation of the methane hydrate decomposition in the process of warm gas injection into a hydratesaturated reservoir [in Russian],” Vestn. Tomsk. Gos. Univ., Mat. Mekh., No. 56, 88–101 (2018).
13. Shagapov V. S., Chiglintseva A. S., and Rusinov A. A., “Theoretical modeling of gas extraction from a partially gas-saturated porous gas-hydrate reservoir with respect to thermal interactions with surrounding rocks,” Theor. Found. Chem. Eng., 50, No. 4, 449–458 (2016).
14. Kalacheva L. P. and Portnyagin A. S., “The influence of electrolytes composition on the dissociation rate of natural gas hydrates obtained in model stratum waters ,” IOP Conf. Ser. Earth Environ. Sci., 272, No. 2 (2019).
15. Semenov M. E., Fedorov A. P., Koryakina V. V., and Ivanova I. K., “Kinetics of formation and decomposition of natural gas hydrates during synthesis from formed ice,” Theor. Found. Chem. Eng., 54, No. 5, 1120–1125 (2020).
16. Kalacheva L. P., Ivanova I. K., Portnyagin A. S., and Ivanov V. K., “Assessment of the possibility of natural and associated petroleum gases storage in the hydrate state ,” SOCAR Proc., Special Issue 1, 99–110 (2022).
17. Kalacheva L. P., Ivanova I. K., Portnyagin A. S., Rozhin I. I., Argunova K. K., and Nikolaev A. I., “Determination of the lower boundaries of the natural gas hydrates stability zone in the subpermafrost horizons of the Yakut arch of the Vilyui syneclise, saturated with bicarbonate-sodium type waters,” SOCAR Proc., Special Issue 2, 1–11 (2021).
18. Kalacheva L. P., Ivanova I. K., and Portnyagin A. S., “Equilibrium conditions of the natural gas hydrates formation in the pore space of dispersed rocks,” IOP Conf. Ser. Earth Environ. Sci., 666, No. 4, Article No. 042062 (2021).
19. Amyx J., Bass D., and Whiting R. L., Petroleum Reservoir Engineering Physical Properties, McGraw-Hill, New York (1960).
20. Basniev K. S., Kochina I. N., and Maksimov V. M., Underground Hydromechanics [in Russian], Nedra, Moscow 1993.
21. Yousif M. H., Abass H. H., Selim M. S., and Sloan E. D., “Experimental and theoretical investigation of methane-gas-hydrate dissociation in porous media,” SPE Reservoir Eng., 6, No. 1, 69–76 (1991).
22. Wolf A. A., Features of the process of decomposition of gas hydrates in porous media [in Russian], Diss. . . . Kand. Fiz.-Mat. Nauk, Tyumen. Filial ITPM SO RAN, Tyumen (1999).
Review
For citations:
Ivanov V.A., Rozhin I.I. Numerical study of natural gas hydrate dissociation in a laboratory sandstone sample under a depression regime. Mathematical notes of NEFU. 2023;30(1):72-88. (In Russ.) https://doi.org/10.25587/SVFU.2023.59.65.006
JATS XML